定向爆破技术在水泥厂窑尾框架拆除中的应用

广西鱼峰太阳村5 500 t/d熟料生产线项目是在拆除老线的基础上新建，老线总高75 m的窑尾框架需要拆除。拆除场地狭小，且附近有已有建筑需要保护，采用定向爆破技术进行拆除。在实施爆破过程中，选取合理的爆破参数，通过精心组织施工，在爆破过程中成功保护了需要保护的建筑。     

Effect of ball-milling parameters on the rheological properties of mold powder slurry

In this study, mold powder slurries with high solid loading and low viscosity were prepared during the ball-milling process for improving the homogeneity and mechanical properties of granules after spray-drying. The effect of ball-milling parameters, such as solid loading, binder/dispersant content, and ball-milling time, on the flowability, dispersibility, stability, and rheological behavior of mold powder slurries was systematically investigated by rheology observation and sedimentation tests. As these parameters varied, the slurry exhibited the shear-thinning behavior of a non-Newtonian fluid with a shear rate range of 0–50 s^?1, which was adequately described by the Herschel-Bulkley model. The optimal parameters that optimized the flowability, dispersibility, and stability of the slurry, along with its rheological behavior, were chosen as follows: solid loading, 60 wt%; modified sodium carboxymethyl cellulose binder content, 1.0 wt%; sodium tripolyphosphate dispersant content, 0.5 wt%; ball-milling time, 60 min.     

Effects of injection parameters on propagation patterns of hydrogen-fueled rotating detonation waves

Two-dimensional rotating detonation waves (RDWs) with separate injections of hydrogen and air are simulated using the Navier–Stokes equations together with a detailed chemical mechanism. The effects of injection stagnation temperature and slot width on the detonation propagation patterns are investigated. Results find that extremely high temperatures can lead to a chaotic mode in which detonation waves are generated and extinguished randomly. Increasing the slot width can reduce the number of detonation waves and finally trigger detonation quenching at a low injection stagnation temperature. But increasing the slot width can change the RDW propagation pattern from a chaotic to a stable mode under high injection temperature. Furthermore, the kinetic parameter τ (representing the chemical reactivity of the mixture) and the kinematic parameter α (representing the mixing efficiency of hydrogen and oxygen) are introduced to distinguish the RDW propagation patterns.     

Synthesis,structure identification and linear/nonlinear optics of hydrothermally grown WO3 nanostructured thin film/FTO: Novel approach

Thin film of WO₃ has been deposited on conductive fluorine tin oxide substrate using the hydrothermal technique. The film's microstructural, morphological and optical properties have been identified using X-ray diffraction, atomic force microscope, and spectrophotometer. The obtained results have confirmed the nanocrystalline structure of the as-received WO₃ thin film with crystallite size ≈63.4 nm. Analysis of the absorption coefficient using Tauc's model shows the possibility of direct and/or indirect allowed transition with energy gaps 3.95 and/or 3.45 eV, respectively. The refractive index has been determined by different methods showing the average value (2.2 and 2.3 corresponding to the direct and indirect transitions, respectively). The nonlinear refractive index and third-order nonlinear optical susceptibility have been determined, showing the high polarizability of WO₃/FTO with radiation to be promising for different optical devices and applications.     

Catalytical enhancement on hydrogen production from LiAlH4 by Fe–Fe2O3 addition

Hydrogen storage technology plays an important role on the development of hydrogen fuel cell and lithium aluminum hydride is a powerful candidate for solid-state hydrogen storage materials. However, the high stability and slow dehydrogenation kinetics of LiAlH₄ hinder its application. In this paper, the two-step thermal decomposition properties of LiAlH₄ with and without Fe–Fe₂O₃ catalysts are investigated. According to the master plots, the model of mample power law (Pn) and nucleation and growth (An) are the optimal mechanism functions for the two-step decomposition of LiAlH₄, respectively. After doping catalysts, the activation energies decrease significantly. The theoretical and optimized kinetic method are consistent with each other on activation energy. And the latter can also yield other kinetic parameters for a more comprehensive kinetic modelling of LiAlH₄ decomposition. Furthermore, Fe–Al₂O₃ and Fe–Al intermetallics generated during dehydrogenation might significantly improve the hydrogen release properties of LiAlH₄.     

特大悬索桥顺层山脊重力式锚碇基坑爆破开挖

爆破开挖山脊重力式锚碇基坑,势必扰动溶蚀严重顺层山体,易致岩体塌落和岩层滑动,影响后期锚碇稳定,特别是类似于赤水河特大桥情况,控制爆破扰动至关重要。针对特大桥特殊的地貌,复杂的地质构造,结合锚碇基坑开挖轮廓设计线,依据爆破地震波能流密度分布主方向及其大小特征等爆源因素相干性等控制爆破理论,对特大桥顺层山脊重力式锚碇基坑爆破开挖参数进行研究,提出了适宜的开挖工艺,经监测岩层损伤在控制范围内。     

Failure load prediction and optimisation for adhesively bonded joints enabled by deep learning and fruit fly optimisation

Adhesively bonded joints have been extensively employed in the aeronautical and automotive industries to join thin-layer materials for developing lightweight components. To strengthen the structural integrity of joints, it is critical to estimate and improve joint failure loads effectually. To accomplish the aforementioned purpose, this paper presents a novel deep neural network (DNN) model-enabled approach, and a single lap joint (SLJ) design is used to support research development and validation. The approach is innovative in the following aspects: (i) the DNN model is reinforced with a transfer learning (TL) mechanism to realise an adaptive prediction on a new SLJ design, and the requirement to re-create new training samples and re-train the DNN model from scratch for the design can be alleviated; (ii) a fruit fly optimisation (FFO) algorithm featured with the parallel computing capability is incorporated into the approach to efficiently optimise joint parameters based on joint failure load predictions. Case studies were developed to validate the effectiveness of the approach. Experimental results demonstrate that, with this approach, the number of datasets and the computational time required to re-train the DNN model for a new SLJ design were significantly reduced by 92.00% and 99.57% respectively, and the joint failure load was substantially increased by 9.96%.     

Reactive sintering process and thermoelectric properties of boron rich boron carbides

Dense boron rich boron carbides were reactive sintered by hot pressing at 2050 °C using elementary boroncarbon compositions with carbon contents of 9.1, 11.1, 13.3 and 18.8 at.%. The following material characteristics are presented: relative density, SEM images, EDX, X-ray diffraction and corresponding lattice parameters, Seebeck coefficient, electrical conductivity and thermoelectric power factor. Significant grain growth has been obtained with increasing boron content. A deeper understanding of the boron and carbon reaction and the overall sintering process is gained by thermal and chemical analysis in combination with X-ray diffraction. Additionally a thermal experiment with boron and carbon layers illustrates the solid state diffusion behaviour. The found results of boron carbide properties of this paper correspond with results by other authors. The aim is to correlate technological aspects of sintering procedure with material properties. This should help to improve the thermoelectric efficiency of boron carbide based materials.     

基于可编程逻辑控制器的电镀工艺参数自动化监控

以可编程逻辑控制器(PLC)为控制核心,辅助相关执行元器件,对电镀过程中涉及的部分关键工艺参数实施自动化监控。分模块阐述了监控原理,并结合实验进行效果验证和评定。结果表明:应用PLC控制系统,可实现工艺参数自动化、实时、准确监控,并且可获得较理想的电镀质量。